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Issue date: 24-September-2015Revision date: 11-April-2019Supersedes date: 23-August-2017Version number: 03SAFETY DATA SHEET1. IdentificationProduct identifierElanco AH0493 Extinosad Pour-On for SheepOther means of identificationSynonymsSpinosad pour-on for sheep and cattle * Spinosad formulation * 232105 formulationItem CodeAH0493Recommended use of the chemical and restrictions on useVeterinary ProductRecommended useRestrictions on useNot available.Details of manufacturer or importerCompany nameAddressTelephoneE-mail24 hr emergency contactnumber24 hr emergency contactnumber (Local)Elanco Australasia Pty LtdMacquarie ParkLevel 3, 7 Eden Park DriveSydney AU 2113 61 1800 226 324elanco [email protected] 0800 293 702 (Freephone)CHEMTREC 61 2 9037 2994 (Local)2. Hazard(s) identificationClassification of the hazardous chemicalNot classified.Physical hazardsHealth hazardsSerious eye damage/eye irritationCategory 2AEnvironmental hazardsHazardous to the aquatic environment, acutehazardCategory 2Hazardous to the aquatic environment,long-term hazardCategory 2Label elements, including precautionary statementsHazard symbol(s)Exclamation EnvironmentmarkSignal wordWarningHazard statement(s)Causes serious eye irritation. Toxic to aquatic life with long lasting effects.Precautionary statement(s)PreventionWear eye/face protection. Wash hands thoroughly after handling.ResponseIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.StorageNot available.DisposalNot available.Material name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA1 / 10
Other hazards which do notresult in classificationNone known.Supplemental informationNone.3. Composition/information on ingredientsMixtureIdentity of chemical ingredientsSpinosadPropylene glycolTrimethylnonanol Polyethylene GlycolLactic acidComposition commentsCAS number and otherunique identifiersConcentration 1-50.5Spinosad is a mixture of the following components: Spinosyn A (CAS# 131929-63-0) and SpinosynD (CAS# 131920-60-7).Remaining components of this product are non-hazardous and/or are present at concentrationsbelow reportable levels.4. First-aid measuresDescription of necessary first aid measuresMove to fresh air. Get medical attention if breathing difficulty occurs. If not breathing, provideInhalationartificial respiration assistance (mouth-to-mouth) and call a physician immediately.Wash off with soap and plenty of water. Take off contaminated clothing and wash before reuse.Skin contactGet medical attention if irritation develops and persists.In case of eye contact, remove contact lens and rinse immediately with plenty of water, also underEye contactthe eyelids, for at least 15 minutes. Get medical attention immediately.If conscious, give the victim plenty of water to drink. Never give anything by mouth to a victim whoIngestionis unconscious or is having convulsions. Call a physician or poison control centre immediately.Personal protection for first-aid In the case of accident or if you feel unwell, seek medical advice immediately (show the labelwhere possible).respondersSymptoms caused by exposure Causes serious eye irritation.Medical attention and specialtreatmentTreat symptomatically.5. Fire-fighting measuresExtinguishing mediaSuitable extinguishingmediaUnsuitable extinguishingmediaWater. Carbon dioxide (CO2). Dry chemicals.Not available.Specific hazards arising fromthe chemicalFire or excessive heat may produce hazardous decomposition products.Special protective equipmentand precautions for firefightersWear self-contained breathing apparatus and protective clothing.Hazchem code3Z6. Accidental release measuresPersonal precautions, protective equipment and emergency proceduresAvoid contact with skin, eyes and clothing. Wear suitable protective clothing, gloves and eye/faceFor non-emergencyprotection. See Section 8 for personal protective equipment. See Section 8 of the SDS forpersonnelPersonal Protective Equipment.For emergency responders Use personal protection recommended in Section 8 of the SDS.Environmental precautionsAvoid discharge into drains, water courses or onto the ground. Prevent spilled material fromflowing onto adjacent land or into streams, ponds, or lakes.Material name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA2 / 10
Methods and materials forcontainment and cleaning upOther issues relating to spillsand releasesSmall Spillages:Use absorbent/adsorbent material to solidify liquids. Sweep up or vacuum up spillage and collectin suitable container for disposal.Large Spillages:Prevent further migration into the environment. Use absorbent/adsorbent material to solidifyliquids. Remove sources of ignition. Local authorities should be advised if significant spillagescannot be contained. Large spills due to traffic accidents, etc., should be reported immediately toCHEMWATCH and Elanco Animal Health for assistance.Clean up in accordance with all applicable regulations.7. Handling and storagePrecautions for safe handlingConditions for safe storage,including any incompatibilitiesAvoid contact with eyes, skin, and clothing. Wash hands thoroughly after handling. Keep awayfrom heat and sources of ignition. Avoid release to the environment.Keep containers tightly closed. Store in a cool, dry place with adequate ventilation. Keep awayfrom incompatible materials, open flames and high temperatures. Avoid contact with oxidisingagents. Do not store in open or unlabelled containers.Storage temperature: between 10 C (50 F) and 40 C (104 F).8. Exposure controls and personal protectionOccupational exposure limitsAustralia. National Workplace OELs (Workplace Exposure Standards for Airborne Contaminants, Appendix A)FormComponentsTypeValuePropylene glycol (CAS57-55-6)TWA474 mg/m310 mg/m3150 ppmTotal vapour andparticulates.Particulate.Total vapour andparticulates.Australia. OELs. (Adopted National Exposure Standards for Atmospheric Contaminants in the pylene glycol (CAS57-55-6)TWA474 mg/m310 mg/m3UK. EH40 Workplace Exposure Limits (WELs)ComponentsTypePropylene glycol (CAS57-55-6)TWATotal vapour andparticulates.Particulate.150 ppmTotal vapour andparticulates.ValueForm474 mg/m3Total vapour andparticulates.Particulate.10 mg/m3150 ppmTotal vapour andparticulates.Biological limit valuesNo biological exposure limits noted for the ingredient(s).Exposure guidelinesSupplier: TWA 0.3 mg/m3 (Spinosad)A Lilly exposure guideline has not been established. The above exposure guideline has beenestablished by the supplier.Use appropriate control measures such as fume hood, ventilated enclosure, local exhaustventilation, or down-draft booth.Appropriate engineeringcontrolsIndividual protection measures, for example personal protective equipment (PPE)Wear goggles/face shield. (AS/NZS 1337)Eye/face protectionSkin protectionHand protectionOtherChemical resistant gloves. (AS/NZS 2161)Chemical-resistant gloves and impermeable body covering to minimize skin contact.Material name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA3 / 10
Respiratory protectionThermal hazardsHygiene measuresSelect appropriate respirator for physical characteristics of material. Select respirator withappropriate protection factor. Respirator selection must be based on known or anticipatedexposure levels, the hazards of the product and the safe working limits of the respirator. (AS/NZS1715)Not available.Use good industrial hygiene practices in handling this material.In a manufacturing setting, wear chemical-resistant gloves and body covering to minimize skincontact. If handled in a ventilated enclosure, as in a laboratory setting, respirator and goggles orface shield may not be required. Safety glasses are always required.When mixing and handling, use protective clothing, impervious gloves, and dust respirator(recommended). Operators should wash thoroughly with soap and water after handling. Ifaccidental eye contact occurs, immediately rinse with plenty of water.Under normal use and handling conditions, wear goggles to protect eyes and wear impermeablegloves and protective equipment to avoid direct contact with skin. Wash thoroughly with soap andwater after handling.9. Physical and chemical propertiesAppearanceClear. low viscosity liquidPhysical stateLiquid.FormLiquid.ColourBlueOdourEarthyOdour thresholdNot available.pH4 - 4.1Melting point/freezing pointNot available.Initial boiling point and boilingrangeNot available.Flash point 62.0 C ( 143.6 F) Pensky-Martens Closed CupEvaporation rateNot available.Flammability (solid, gas)Not applicable.Upper/lower flammability or explosive limitsNot available.Flammability limit - lower(%)Flammability limit - upper(%)Not available.Explosive limit - lower ( %)Not available.Explosive limit – upper(%)Not available.Vapour pressureNot available.Vapour densityNot available.Relative densityNot available.Solubility(ies)Solubility (water)SolublePartition coefficient(n-octanol/water)Not available.Auto-ignition temperatureNot available.Decomposition temperatureNot available.ViscosityNot available.Other physical and chemical parametersNot explosive.Explosive propertiesOxidising propertiesThe substance or mixture is not classified as oxidizing.Specific gravity1.023Material name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA4 / 10
10. Stability and reactivityReactivityNot water reactive.Chemical stabilityMaterial is stable under normal conditions.Possibility of hazardousreactionsHazardous polymerisation does not occur.Conditions to avoidNone known.Incompatible materialsStrong oxidising agents.Hazardous decompositionproductsFire or excessive heat may produce hazardous decomposition products.11. Toxicological informationAcute toxicityProductBased on available data, the classification criteria are not met.SpeciesTest ResultsElanco AH0493 Extinosad Pour-On for SheepAcuteDermalLiquidLD50Rabbit 1000 mg/kgOralLiquidLD50Rat 5000 mg/kgSpeciesTest ResultsDermalLD50Rabbit 2000 mg/kg No MortalityInhalationLC50Rat 7.94 mg/l, 4 hOralLD50Rat3543 - 4936 mg/kgDermalLD50Rabbit22 g/kgOralLD50Rat20.8 g/kgDermalLDRabbit 5000 mg/kgInhalationLC50Rat 5180 mg/m3, 4 hoursOralLD50Rat 2000 mg/kgComponentsLactic acid (CAS 50-21-5)AcutePropylene glycol (CAS 57-55-6)AcuteSpinosad (CAS 168316-95-8)AcuteTrimethylnonanol Polyethylene Glycol (CAS 60828-78-6)AcuteDermalLD50Rabbit8874 mg/kgOralLD50Rat3300 mg/kgMaterial name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA5 / 10
Rabbit: No irritation.Based on available data, the classification criteria are not met.Rabbit: Severe eye irritation.Skin corrosion/irritationSerious eye damage/irritationRespiratory or skin sensitisationDue to lack of data the classification is not possible.Respiratory sensitisationGuinea pig: Did not cause sensitization on laboratory animals.Based on available data, the classification criteria are not met.In vitro and in vivo tests did not show mutagenic effects. (Spinosad) (Propylene Glycol)(Polydimethylsiloxane)Based on available data, the classification criteria are not met.Skin sensitisationGerm cell mutagenicityCarcinogenicityNo effects identified in animal studies. (Spinosad) (Propylene Glycol)Based on available data, the classification criteria are not met.Reproductive toxicityIn laboratory animal studies, effects on reproduction have been seen only at doses that producedsignificant toxicity to the parent animals. (Spinosad)No effects identified in animal studies. (Propylene Glycol)Based on available data, the classification criteria are not met.Specific target organ toxicity single exposureDue to lack of data the classification is not possible.Specific target organ toxicity repeated exposureIn animals, has been shown to cause vacuolation of cells in liver, kidney, and bone tissues andchanges in blood and serum biochemistry. Dose levels producing these effects were many timeshigher than any dose levels expected from exposure due to use. (Spinosad)Based on available data, the classification criteria are not met.Aspiration hazardDue to lack of data the classification is not possible.12. Ecological informationEcotoxicityToxic to aquatic life with long lasting effects.ComponentsSpeciesTest ResultsEC50Selenastrum capricornutum (new namePseudokirchnerella subca3500 mg/l, 72 hNOECSelenastrum capricornutum (new namePseudokirchnerella subca1900 mg/l, 72 hAquaticAcuteFishLC50Oncorhynchus mykiss130 mg/l, 96 hChronicFishLOECFish2.18 mg/l, 90 dLactic acid (CAS 50-21-5)AcuteChronicPropylene glycol (CAS 57-55-6)AquaticAcuteCrustaceaEC50Water flea (Daphnia magna)43500 mg/l, 48 hoursFishLC50Rainbow trout,donaldson trout(Oncorhynchus mykiss)51600 mg/l, 96 hoursErC50Navicula pelliculosa0.079 mg/l, 120 h (static)NOECNavicula pelliculosa0.036 mg/lAquaticAlgaeNOECDuckweed (Lemna minor)1.4 mg/lCrustaceaEC50Daphnia7.37 mg/l, 48 hWater flea (Daphnia magna) 1 mg/l, 48 h (static)NOECWater flea (Daphnia magna)0.0012 mg/l, 21 days (flow thorugh)LC50Carp (Cyprinus carpio)4.5 mg/l, 96 h (flow through)Spinosad (CAS 168316-95-8)FishMaterial name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA6 / 10
ComponentsNOECSpeciesTest ResultsOncorhynchus mykiss0.5 mg/l Early life-stage (flow through)Trimethylnonanol Polyethylene Glycol (CAS 60828-78-6)AquaticAcuteCrustaceaLC50Daphnia magna81.2 mg/l, 48 hFishLC50Fish39 mg/l, 96 hPersistence and degradabilityNo data is available on the degradability of this product.Bioaccumulative potentialNo data available on bioaccumulation.Partition coefficientn-octanol / water (log Kow)Lactic acidPropylene glycol-0.72-0.92Bioconcentration factor(BCF)Spinosad 500Mobility in soilNot available.Other adverse effectsHighly Toxic to honey bees, oysters and diatoms. Moderately toxic to fish and aquaticinvertebrates. No more than slightly to practically non-toxic to birds. Practically non-toxic to greenalgae. No volatility expected. Does not bioconcentrate in aquatic organisms. Not persistent due tophotolysis and biodegradation. (Spinosad)13. Disposal considerationsDisposal methodsDo not allow this material to drain into sewers/water supplies. Dispose of contents/container inaccordance with local/regional/national/international regulations.14. Transport informationGeneral informationEffective January 1, 2015 by Special Provision, UN3077 and UN3082 when packaged in innerpackages of 5L / 5 KG or less are not subject to the dangerous goods regulations.ADG3082UN numberENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SPINOSAD)UN proper shipping nameTransport hazard class(es)9ClassSubsidiary riskIIIPacking groupYesEnvironmental hazards 3ZHazchem codeSpecial precautions for user Not available.Not classified as dangerous goods when transported by road or rail in packaging or receptacles not exceeding 500 kg (L)according to ADG 7 SP AU01.RID3082UN numberEnvironmentally hazardous substance, liquid, n.o.s. (Spinosad)UN proper shipping nameTransport hazard class(es)9ClassSubsidiary risk9Label(s)IIIPacking groupYesEnvironmental hazardsSpecial precautions for user Read safety instructions, SDS and emergency procedures before handling.IATA3082UN numberEnvironmentally hazardous substance, liquid, n.o.s. (Spinosad)UN proper shipping nameTransport hazard class(es)9ClassSubsidiary riskIIIPacking groupMaterial name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA7 / 10
Environmental hazardsERG CodeSpecial precautions for userOther informationPassenger and cargoaircraftCargo aircraft onlyIMDGUN numberUN proper shipping nameTransport hazard class(es)ClassSubsidiary riskPacking groupEnvironmental hazardsMarine pollutantEmSSpecial precautions for userTransport in bulk according toAnnex II of MARPOL 73/78 andthe IBC CodeYes9LRead safety instructions, SDS and emergency procedures before handling.Allowed with restrictions.Allowed with restrictions.3082Environmentally hazardous substance, liquid, n.o.s. (Spinosad)9IIIYesF-A, S-FRead safety instructions, SDS and emergency procedures before handling.Not available.ADG; IATA; IMDG; RIDMarine pollutant15. Regulatory informationSafety, health and environmental regulationsNational regulationsAPVMA approval number 60117Australia Medicines & Poisons Appendix APoisons schedule number not allocated.Australia Medicines & Poisons Appendix BPropylene glycol (CAS 57-55-6)Australia Medicines & Poisons Appendix DPoisons schedule number not allocated.Australia Medicines & Poisons Appendix EPoisons schedule number not allocated.Australia Medicines & Poisons Appendix FPoisons schedule number not allocated.Australia Medicines & Poisons Appendix GPoisons schedule number not allocated.Material name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA8 / 10
Australia Medicines & Poisons Appendix HPoisons schedule number not allocated.Australia Medicines & Poisons Appendix IPoisons schedule number not allocated.Australia Medicines & Poisons Appendix JPoisons schedule number not allocated.Australia Medicines & Poisons Appendix KPoisons schedule number not allocated.Australia Medicines & Poisons Schedule 10Poisons schedule number not allocated.Australia Medicines & Poisons Schedule 2Poisons schedule number not allocated.Australia Medicines & Poisons Schedule 3Poisons schedule number not allocated.Australia Medicines & Poisons Schedule 4Poisons schedule number not allocated.Australia Medicines & Poisons Schedule 5Poisons schedule number not allocated.Australia Medicines & Poisons Schedule 6Poisons schedule number not allocated.Australia Medicines & Poisons Schedule 7Poisons schedule number not allocated.Australia Medicines & Poisons Schedule 8Poisons schedule number not allocated.Australia Medicines & Poisons Schedule 9Poisons schedule number not allocated.High Volume Industrial Chemicals (HVIC)Propylene glycol (CAS 57-55-6)10000 - 99999 TONNES See the regulation for additionalinformation.Importation of Ozone Deleting Substances (Customs(Prohibited imports) Regulations 1956, Schedule 10)Not listed.National Pollutant Inventory (NPI) substance reporting listNot listed.Prohibited Carcinogenic SubstancesNot regulated.Prohibited Substances (National Model Regulation for the control of Workplace Hazardous Substances, Schedule 2NOHSC:1005 (1994) as amended)Not listed.Resricted Importation of Organochlorine Chemicals (Customs(Prohibited Imports) Regulations 1956, Schedule 9)Not listed.Restricted Carcinogenic SubstancesNot regulated.International regulationsStockholm ConventionNot applicable.Rotterdam ConventionNot applicable.Kyoto ProtocolNot applicable.Montreal ProtocolNot applicable.Basel ConventionNot applicable.International InventoriesCountry(s) or regionAustraliaInventory nameAustralian Inventory of Chemical Substances (AICS)Material name: Elanco AH0493 Extinosad Pour-On for Sheep4890On inventory (yes/no)*NoSDS AUSTRALIA9 / 10
Country(s) or regionCanadaInventory nameDomestic Substances List (DSL)CanadaNon-Domestic Substances List (NDSL)NoChinaInventory of Existing Chemical Substances in China (IECSC)NoEuropeEuropean Inventory of Existing Commercial ChemicalSubstances (EINECS)NoEuropeEuropean List of Notified Chemical Substances (ELINCS)NoJapanInventory of Existing and New Chemical Substances (ENCS)NoKoreaExisting Chemicals List (ECL)NoNew ZealandNew Zealand InventoryPhilippinesPhilippine Inventory of Chemicals and Chemical Substances(PICCS)TaiwanTaiwan Chemical Substance Inventory (TCSI)United States & Puerto RicoToxic Substances Control Act (TSCA) InventoryOn inventory (yes/no)*NoYesNoYesNo*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).16. Other informationIssue date24-September-2015Revision date11-April-2019DisclaimerAs of the date of issuance, we are providing available information relevant to the handling of thismaterial in the workplace. All information contained herein is offered with the good faith belief thatit is accurate. THIS SAFETY DATA SHEET SHALL NOT BE DEEMED TO CREATE ANYWARRANTY OF ANY KIND (INCLUDING WARRANTY OF MERCHANT ABILITY OR FITNESSFOR A PARTICULAR PURPOSE). In the event of an adverse incident associated with thismaterial, this safety data sheet is not intended to be a substitute for consultation with appropriatelytrained personnel. Nor is this safety data sheet intended to be a substitute for product literaturewhich may accompany the finished product.Revision informationFor additional information contact:Elanco Animal Health0011 1-877-352-62610011 1-800-428-4441Handling and storage: Conditions for safe storage, including any incompatibilitiesExposure controls and personal protection: Hand protectionPhysical & Chemical Properties: Multiple PropertiesPhysical and chemical properties: Explosive propertiesToxicological Information: Toxicological Property DataToxicological information: CorrosivityOther information: DisclaimerOther information: Key abbreviations or acronyms usedGHS: ClassificationMaterial name: Elanco AH0493 Extinosad Pour-On for Sheep4890SDS AUSTRALIA10 / 10
Classification of the hazardous chemical . In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. . Other Chemical-resistant gloves and impermeable body covering to minimize skin contact. 3 / 10 Material
